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MSDS-Material Safety Date Sheet
1.Hazardous Ingredients/Identity Information
Hazardous Components
|
Component |
No.
CAS |
%
Weight |
OSHAPEL
(TLV) |
LD50
Ora |
LD50
Inhalation |
LD50
Contact |
|
Lead
Pb, Pb02, PbSo4 |
7439-92-1 |
65-75% |
0.050mg/m3 |
<
500 mg/kg |
<
20 mg/m3 |
N/A |
|
Sulfuric
Acid |
7664-93-9 |
17-30% |
1
mg/m3 |
2.140
kg/kg |
18
mg/m3 |
135
mg/kg |
Physical Data
|
Component |
Density |
Solubility
in water |
Odor |
Appearance |
|
Lead |
11.34
mg/cm3 |
None |
None |
Silver-gray
metal |
|
Lead
Sulfate |
6.20
gm/cm3 |
43
mg/l |
None |
White
powder |
|
Lead
Dioxide |
9.375
gm/cm3 |
None |
None |
Brown
powder |
|
Sulfuric
Acid |
1.290
gm/cm3 |
100% |
None |
Clear
liquid |
Flammability
|
Component |
Flash
point |
Expansive
Limits |
Comments |
|
Lead |
None |
None |
Use
" ABC" Type fire extinguisher for battery
fires |
|
Sulfuric
Acid |
None |
None |
CCB |
|
Hydrogen |
<0
oF |
4%-74.2% |
Power
batteries can emit hydrogen only if over charged (float
voltage 2.40 VPC or greater) |
2. Health Hazard Information
Under normal operating conditions, the internal material will
not be hazardous to your health. Only internally exposed material
during production or case breakage or extreme heat (fire)
may be hazardous to your health.
Routes of Entry:
1. Installation: Acid mist from formation process may cause
respiratory irritation.
2. Skin Contact: Acid may cause irritation, burns and/or ulceration.
3. Skin Absorption: Not a significant route of entry.
4. Eye Contact: Acid may cause sever irritation, burns, cornea
damage and/or blindness.
5. Ingestion: Acid may cause irritation of mouth, throat,
esophagus and stomach.
Sign and Symptoms of Over Exposure:
Acute Effects: Over exposure to lead may lead to loss of appetite,
constipation, sleeplessness and fatigue. Over exposure to
acid may lead to skin irritation, corneal damage of the eyes
and upper respiratory system.
Chronic Effects: Lead and its components may cause damage
to kidneys and nervous system. Acid and its components may
cause lung damage and pulmonary conditions.
Potential to Cause Cancer: The International Agency for Research
on Cancer has classified "strong inorganic acid mist
containing sulfuric acid" as a Category 1 carcinogen,
a substance that is carcinogenic to humans. This classification
does not apply to liquid forms of sulfuric acid or sulfuric
acid solutions contained within a battery. Inorganic acid
mist is not generated under normal use of this product. Misuse
of the product, such as overcharging, may however result in
the generation of sulfuric acid mist.
Emergency and First Aid Procedures:
1.Inhalation: Remove from exposure and apply oxygen if breathing
is difficult.
2. Skin: Wash with plenty of soap and water. Remove any contaminated
clothing.
3. Eyes: Flush with plenty of water immediately for at least
15 minutes. Consult a physician.
4. Ingestion: Consult a physician immediately.
3.Fire And Explosion Hazard Data
Flash Point: Hydrogen = 259oC
Auto ignition Temperature: Hydrogen = 580oC
Extinguishing Media: Dry Chemical, foam, CO2
Unusual Fire and Explosion Hazards: Hydrogen and oxygen gases
are produced in the cells during normal battery operation
(hydrogen is flammable and oxygen supports combustion). These
gases enter the air through the vent caps. To avoid the chance
of a fire or explosion, keep sparks and other sources of ignition
away from the battery.
4.Reactivity Data
Stability: Stable
Conditions to Avoid: Sparks and other sources of ignition.
Incompatibility: (materials to avoid)
1.Lead/lead compounds: Potassium, carbides, sulfides, peroxides,
phosphorus, sulfur.
2.Battery electrolyte (acid): Combustible materials, strong
reducing agents, most metals, carbides, organic materials,
chlorates, nitrates, picrates, and fulminates.
Hazardous Decomposition Products:
1.Lead/lead compounds: Oxides of lead and sulfur.
2.Battery electrolyte (acid): Hydrogen, sulfur dioxide, and
sulfur trioxide.
Conditions to Avoid:
High temperature. Battery electrolyte (acid) will react with
water to produce heat. Can react with oxidizing or reducing
agents.
5.Control Measures
Engineering Controls:
Store lead/acid batteries with adequate ventilation. Room
ventilation is required for batteries utilized for standby
power generation. Never re-charge batteries in an unventilated
enclosed space.
Work Practices:
Do not remove vent caps. Follow shipping and handling instructions,
which are applicable to the battery type. To avoid damage
to terminals and seals, do not double-stack industrial batteries.
6.Personal Protective Equipment
Respiratory Protection:
None required under normal handling conditions. During battery
formation (high-rate charge condition), acid mist can be generated
which may cause respiratory irritation. Also, if acid spillage
occurs in a confined space, exposure may occur. If irritation
occurs, wear a respirator suitable for protection against
acid mist.
Eyes and Face:
Chemical splash goggles are preferred. Also acceptable are
"visor-gogs" or a chemical face shield worn over
safety glasses.
Hands, Arms, Body:
Vinyl coated, VC, gauntiet type gloves with rough finish are
preferred.
7.Precautions For Safety Handling And Use
Hygiene Practices:
Following contact with internal battery components, wash hand
thoroughly before eating, drinking, or smoking.
Respiratory Protection:
Wear safety glasses. Do not permit flames or sparks in the
vicinity of battery(s). If battery electrolyte (acid) comes
in contact with clothing, discard clothing.
Protective Measures:
Remove combustible materials and all sources of ignition.
Cover sills with soda ash (sodium carbonate) or quicklime
(calcium oxide). Mix well. Make certain mixture is neutral
then collect residue and place in a drum or other suitable
container. Dispose of a hazardous waste.
Wear acid-resistant boots, chemical face shield, chemical
splash goggles, and acid-resistant gloves. Do not release
un-neutralized acid.
Waste Disposal Method:
Battery electrolyte (acid): Neutralize as above for a spill,
collect residue, and place in a drum or suitable container.
Dispose of as hazardous waste. Do not flush lead contaminated
acid to sewer.

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